Understanding the Flammability of Glycol

Close-up of glycol liquid with fire safety symbol indicating flammability risk

What Is Glycol and Why Is Its Flammability Important?

The flammability of glycol is an essential topic for industries and professionals who handle this versatile chemical. Whether used in HVAC systems, refrigeration, antifreeze, or various industrial processes, glycol’s fire risk cannot be overlooked. Understanding glycol’s flammability properties, safe handling, and storage procedures helps prevent accidents and ensures regulatory compliance. This article explores the key aspects of glycol’s flammability, offering clear guidance to keep your workplace safe and informed.

Glycol is a family of organic compounds known as diols or glycols, widely used for their antifreeze and heat-transfer properties. The two most common types of glycol are ethylene glycol and propylene glycol.

  • Ethylene glycol (EG) is extensively used in automotive antifreeze, HVAC systems, and industrial applications. It is effective as a coolant but is toxic and more flammable than its counterpart.
  • Propylene glycol (PG), considered safer and less toxic, is commonly used in food processing, pharmaceuticals, and less hazardous applications.

Glycol’s importance lies in its ability to transfer heat efficiently, prevent freezing, and act as a solvent. However, its flammability profile varies depending on type, concentration, and environmental conditions. Recognizing these factors is crucial because mishandling glycol can lead to fire hazards, endangering personnel and property.

Flammability is an intrinsic property that describes how easily a substance can ignite and sustain combustion. For glycol, understanding this risk informs proper storage, spill response, and usage protocols—especially in industries where heat, sparks, or open flames may be present.

Flammability Characteristics of Different Types of Glycol

Chart comparing flash points of ethylene glycol and propylene glycol, highlighting their flammability ratings and safe handling temperatures.

Ethylene Glycol vs. Propylene Glycol Flammability

One of the first distinctions to make when discussing the flammability of glycol is the difference between ethylene glycol and propylene glycol. These compounds have different chemical structures and properties influencing their fire risk.

  • Ethylene glycol has a flash point of about 111°C (232°F). The flash point is the lowest temperature at which vapors ignite when exposed to an ignition source. At typical room temperatures, ethylene glycol is not highly volatile, meaning it won’t easily catch fire unless heated significantly.
  • Propylene glycol has a higher flash point, approximately 103°C to 107°C (217°F to 224°F), depending on purity. This higher flash point means propylene glycol is generally less flammable and safer to handle in environments with moderate heat.

Both glycols are classified as combustible liquids rather than highly flammable. This means that while they can ignite, it typically requires elevated temperatures and an ignition source. The National Fire Protection Association (NFPA) rates ethylene glycol as having a flammability rating of 2 (on a scale from 0 to 4), indicating moderate fire hazard.

Influence of Concentration and Temperature

Glycol is rarely used in pure form; it is often diluted with water or other substances. The concentration affects flammability:

  • Higher glycol concentrations have higher flash points, reducing flammability.
  • Diluted glycol solutions tend to have increased water content, which acts as a fire suppressant.

Temperature also plays a critical role. When glycol solutions are heated beyond their flash point, the risk of ignition increases. In hot industrial processes, heating glycol without proper controls can create dangerous conditions.

Safety Precautions When Handling Flammable Glycol

Proper Storage Recommendations

Storing glycol correctly is one of the most effective ways to reduce fire risk. Here are best practices:

  • Store glycol in cool, well-ventilated areas away from direct sunlight and heat sources.
  • Use approved containers designed for chemical storage that seal tightly to prevent vapor leaks.
  • Keep glycol away from ignition sources such as sparks, open flames, electrical equipment, or hot surfaces.
  • Maintain separation from incompatible materials, such as strong oxidizers, which could react and increase fire hazards.

Following these recommendations reduces the likelihood of vapor buildup and accidental ignition.

Handling Spills and Leaks Safely

Accidental spills or leaks can pose immediate fire hazards and environmental damage. Safe handling includes:

  • Containing spills quickly using absorbent materials such as sand or commercial spill kits.
  • Preventing the spilled glycol from entering drains, waterways, or soil.
  • Cleaning spills promptly while wearing appropriate personal protective equipment (PPE)—gloves, goggles, and respirators if necessary.

Reporting large spills to environmental or fire authorities per local regulations.

Ventilation and Protective Equipment

Proper ventilation is crucial in enclosed spaces where glycol vapors may accumulate. Ensure HVAC systems provide sufficient airflow to dissipate vapors safely.

Workers handling glycol should always wear PPE that protects skin and eyes from contact, and respiratory protection if vapor concentrations exceed safety limits.

Emergency Response to Glycol Fires

In the event of a glycol fire:

  • Use foam, dry chemical, or carbon dioxide (CO2) extinguishers to suppress flames.
  • Avoid using water directly as it can spread the glycol and potentially exacerbate the fire.
  • Evacuate personnel and notify emergency services immediately.

Refer to the Occupational Safety and Health Administration (OSHA) guidelines for chemical fire safety: OSHA Chemical Safety.

Environmental and Regulatory Considerations

Regulations for Glycol Storage and Fire Safety

Compliance with regulations ensures safe use of glycol and legal operation:

  • The Environmental Protection Agency (EPA) regulates glycol disposal and spill reporting to prevent contamination.
  • The NFPA 30 (Flammable and Combustible Liquids Code) provides detailed guidelines on the storage, handling, and fire protection of combustible liquids like glycol.

Local fire codes may impose additional requirements for facility design and emergency preparedness.

Environmental Impact of Glycol Fires and Spills

Glycol spills can threaten water quality, aquatic life, and soil health. When glycol burns, it can produce toxic fumes harmful to people and the environment.

Industries must employ containment systems, proper disposal methods, and emergency plans to minimize environmental damage. Companies like Red River specialize in consulting for regulatory compliance and safe chemical handling.

Key Points on the Flammability of Glycol

Understanding the flammability of glycol is vital for anyone working with this chemical. Ethylene glycol and propylene glycol differ in their fire risks, with ethylene glycol being moderately flammable and propylene glycol generally safer. Storage conditions, concentration, and temperature all influence glycol’s ignition potential.

Safety depends on proper handling protocols, appropriate storage, spill management, and emergency preparedness. Adhering to environmental and fire safety regulations further protects people and property. With the right knowledge and precautions, the risks associated with glycol’s flammability can be effectively managed.

Need a reliable partner?​

Red River specializes in the design and manufacturing of pressure vessels. We also fabricate related items such as prefabricated spools and skid packages.

Reach out to us today and experience the Red River difference. Where American-made products and American Values come together, we care more.

Frequently Asked Questions

1. Is glycol flammable?

Yes, some types of glycol, especially ethylene glycol, are flammable under certain conditions, mainly when heated near or above their flash points.

2. What is the flash point of glycol?

Ethylene glycol’s flash point is around 111°C (232°F), while propylene glycol’s flash point is higher, approximately 103°C to 107°C (217°F to 224°F), making it less flammable.

3. Can glycol catch fire easily?

No, glycol does not ignite easily at room temperature. It requires elevated heat or an ignition source to catch fire.

4. How should glycol be stored to reduce fire risk?

Store glycol in cool, ventilated areas away from ignition sources and in sealed, approved containers.

5. Are there environmental risks if glycol catches fire?

Yes, burning glycol releases toxic fumes that can harm people and the environment.

6. Is propylene glycol safer than ethylene glycol?

Propylene glycol is generally less toxic and less flammable, making it safer for many applications.

7. What personal protective equipment (PPE) is recommended?

Use gloves, goggles, and respiratory protection when handling glycol to prevent exposure.

8. How do you extinguish a glycol fire?

Use foam, dry chemical, or CO2 extinguishers. Avoid water as it can spread the fire.

Key Takeaways

  • Glycol’s flammability varies by type, with ethylene glycol being more flammable than propylene glycol.
  • Flash points and temperature significantly impact glycol’s fire risk.
  • Safe handling, storage, and spill response reduce fire hazards.
  • Compliance with environmental and fire safety regulations is essential.
  • Using proper PPE and emergency procedures ensures workplace safety.

Need Action?

We are here to make it happen. Request a qoute!

Solutions

In the realm of industrial solutions, Red River emerges as a pioneer, offering a diverse range of custom-engineered products and facilities. Among our specialties is the design and production of Custom/OEM Pressure Vessels, meticulously crafted to meet individual client requirements, ensuring performance under various pressure conditions. Our expertise extends to the domain of prefabrication, where Red River leads with distinction.

The company excels in creating prefabricated facilities, modules, and packages, reinforcing its stance as a forerunner in innovation and quality. This proficiency is further mirrored in their Modular Skids offering, where they provide an array of Modular Fabricated Skid Packages and Packaged equipment. Each piece is tailored to client specifications, underlining their commitment to delivering precision and excellence in every project they undertake.

Pressure Vessel line art

Pressure Vessels

Custom/OEM Pressure Vessels designed to fit your needs.

explore
Prefabrication line art

Prefabrication

Red River is a leader in prefabricated facilities, modules and packages.

explore
Modular skid line art

Modular Skids

Modular Fabricated Skid Packages and Packaged equipment manufactured to your specifications.

explore
Index